Solvent-driven crystal-crystal transformation and morphology change in a 2D layer inorganic POM-based framework
نویسندگان
چکیده
منابع مشابه
Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework.
A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.
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ژورنال
عنوان ژورنال: Nanoscale Advances
سال: 2021
ISSN: 2516-0230
DOI: 10.1039/d1na00416f